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Application of Polyacrylamide in Coal Washing

2024-03-15

Polyacrylamide (PAM) is a versatile polymer that finds applications in various industries, including coal washing. Coal washing is a process used to remove impurities from coal before it is burned for energy production. Polyacrylamide can be applied in coal washing for several purposes. Here are some common applications:

 

1. Solid-liquid separation: Polyacrylamide is used as a flocculant in the coal washing process to promote solid-liquid separation. It helps in agglomerating fine coal particles and settling them faster, resulting in improved solid-liquid separation efficiency. By forming larger and denser flocs, polyacrylamide aids in the sedimentation of coal particles, leading to cleaner coal and reduced water consumption.

 

2. Filtration aids: Polyacrylamide can act as a filtration aid in coal washing. It enhances the cake formation on filter media, improves filtration rates, and reduces moisture content in the final coal product. By facilitating the dewatering process, polyacrylamide helps in reducing the moisture content of coal, which improves its combustion efficiency.

 

3. Foam control: During the coal washing process, foaming can occur, which interferes with the separation and dewatering steps. Polyacrylamide can be used as an antifoaming agent to suppress foam formation and enhance the efficiency of the coal washing process.

 

4. Rheology modification: Polyacrylamide can modify the rheology (flow properties) of the coal washing slurry. By adjusting the viscosity and consistency of the slurry, it helps in controlling the flow rate, improving mixing efficiency, and reducing sedimentation and settling time.

 

It's worth noting that the specific application and dosage of polyacrylamide in coal washing may vary depending on the coal characteristics, washing process, and plant conditions. The selection of the appropriate molecular weight and charge characteristics of polyacrylamide is crucial to achieve desired results in coal washing operations. Additionally, it's important to handle and use polyacrylamide in accordance with safety guidelines and environmental regulations to minimize any potential risks associated with its use.

functions of polyurethane binder in printing ink

2024-03-15

The functions of polyurethane resin in inks are as follows:

1. Excellent yellowing resistance.
Polyurethane resin for ink is mainly synthesized from aliphatic polyester and aliphatic isocyanate as the main raw materials during the preparation process. Compared with aromatic polyurethane, it has excellent optical stability, and the film has excellent Yellowing resistance.
2. Excellent adhesion fastness to film substrates.
The molecular segments of the polyurethane binder for ink contain polar groups such as urethane, allophanate, ester bonds, and ether bonds, and are compatible with a variety of polar substrates, PET The polar groups on the surface of plastics such as PA and PA form hydrogen bonds, thereby forming joints with a certain connection strength. After the polyurethane resin is made into ink, it has good adhesion fastness when printed on the surface of polar plastic substrates.
3. Has good affinity and wettability with pigments
Polyurethane resin for ink is generally prepared from polyester or polyether polyol, alicyclic diisocyanate and diamine/diol chain extender. Due to the introduction of urea bonds in PU resin, polyurethane-urea resin (PUU) is formed, which makes it have good dispersion and wetting properties for pigments.

4. Good resin compatibility.
Polyurethane resin for ink has good compatibility with aldehyde-ketone resin, chlorine-vinegar resin, etc., and can be appropriately added to your own process formula according to actual conditions to improve the overall performance of the ink.
5.Excellent film-forming properties
The structure of ink polyurethane resin is different from the polyurethane resin used in other fields. Traditional polyurethane mainly reacts with polyester polyol/polyether polyol and isocyanic acid to form hydroxyl-terminated polyurethane resin. The polar group in the molecular structure is aminomethyl. Mainly acid ester, the molecular cohesion is not enough to meet the film-forming performance requirements of resin for ink. Therefore, polyurethane resin for ink introduces urea group on the basis of traditional polyurethane to greatly improve the cohesive strength and film-forming properties of the resin itself.
6. Good solvent release:

The dissolving effect of organic solvents on resin is to attract solute molecules through the polarity of solvent molecules, which is commonly known as like dissolves. Traditional polyurethane resins have a wide range of compatibility with organic solvents. However, in the process of making inks, in order to adjust the ink flow properties and viscosity, alcoholic organic solvents need to be added. This will greatly reduce the stability of the resin system for traditional polyurethane resins. properties, turbidity, flocculent precipitation and other incompatibility phenomena may occur. However, the polyurethane resin used in ink is miscible with alcohol due to the presence of urea groups, but it should be noted that alcohol solvents are still pseudo-solvents. In the microscopic state, alcohol solvents wrap the polyurethane resin molecules, rather than true solvents due to the polarity of the molecules. Penetrating through the molecule, the ink made of polyurethane resin has good fluidity.

 

Polyurethane resin is a versatile material that can be used in the preparation of gravure printing ink for film. Gravure printing is a method of printing that uses engraved cylinders to transfer ink onto a substrate, and it is commonly used for high-volume printing applications such as packaging and labeling.

as a binder to provide adhesion and durability to the ink. It can also be used to adjust the viscosity and flow properties of the ink, which is important for ensuring consistent print quality and optimal ink transfer to the substrate.

We could provide solvent based polyurethane resin, polyurethane emulsion, acrylic resin, waterborne polyurethane dispersion to meet diversified requirement.


 

Application of polyurethane binder in film printing ink

2024-03-15

The liquid part of the ink component is called the binder; the solid component is the color material (pigment or dye); and various additives.The connecting material is a colloidal fluid with a certain viscosity. Its function is first to serve as a carrier for pigments, mixing and connecting solid particles such as powdered pigments. The pigments are evenly dispersed in it, relying on its wetting effect. , it is easier to be ground finely on the grinding machine; secondly, it serves as a binder to enable the pigment to be finally fixed on the surface of the substrate to achieve the purpose of displaying text, images, marks, decoration, etc.It is also relying on its adhesion function that the ink can be transferred and delivered on the printing press.Finally, on the printed matter, the connecting material also plays the role of a protective film, presents the necessary gloss, and can even protect the substrate.

The quality of the connecting material directly affects the performance of the ink, because the connecting material determines the viscosity, stickiness, dryness, fluidity and other properties of the ink to a large extent.If you want to get high-quality ink, you must use high-quality connecting materials.The various properties of the ink binder determine the various adaptability of the printing ink. The resins used in plastic gravure printing inks generally include chlorinated polypropylene, polyamide, polyurethane, etc.For a long time, chlorinated polypropylene has occupied most of the resin market for gravure composite back printing inks due to its low price and excellent adhesion to OPP. However, its biggest shortcoming is that its main solvent is toluene, and environmentally friendly solvents such as ester are usually used. Alcohol-based solvents are ineffective. Solvent-based polyurethane binder for ink has the advantages of easy use, stable performance, strong adhesion, excellent gloss, and good heat resistance. It can meet the requirements of various printing methods, especially suitable for screen printing, plastic packaging, and composite films. aspect.Industrialization has been achieved in foreign countries in the 1970s, such as Toyo Corporation of Japan, Dainippon Ink Chemical Industries, and Takeda Pharmaceuticals. The polyurethane ink connecting materials used in China are generally polyurethane rubber particles imported from abroad, and then processed and used. The demand reaches 30,000 tons.In recent years, many domestic production and scientific research units have been engaged in the research of polyurethane ink connectors, and have achieved good results. For example, units that can withstand 121°C and 135°C cooking ink connectors have been put into production and are widely promoted and used in the market. , but there is a certain gap between the comprehensive performance of the product and imported products. Improving the comprehensive performance of the product and developing multi-functional products are the focus of domestic research on polyurethane ink connecting materials.

 

The polyurethane resin used in ink is generally formed by the reaction of polyester/polyether polyol and isocyanate, with a molecular force of about 20,000 to 40,000.The solvents are mainly benzene, ketone and ester solvents.During the research and development process, ketone ester solvents or alcohol ester solvents can be used to prepare corresponding benzene-free ink resins according to the environmental protection needs of ink factories and printing factories.

 

Characteristics of polyurethane resin for ink

1. Excellent yellowing resistance

Polyurethane resin for ink is mainly synthesized from aliphatic polyester and aliphatic isocyanate as the main raw materials during the preparation process. It has excellent optical stability compared to aromatic polyurethane, and the film has excellent yellowing resistance after film formation.

2. Excellent adhesion fastness to film substrates

The molecular segments of polyurethane resin for ink contain polar groups such as urethane, allophanate, ester bond, and ether bond, which form with the polar groups on the surface of various polar base materials such as PET and PA. Hydrogen bonds, thereby forming joints with a certain connection strength.After the polyurethane resin is made into ink, it has excellent adhesion fastness when printed on the surface of polar plastic substrates.

3. Good affinity and wettability with pigments/dyes

Polyurethane resin for ink is generally prepared from polyester or polyether polyol, alicyclic diisocyanate and diamine/diol chain extender, with a molecular weight of approximately tens of thousands.Due to the introduction of urea bonds in PU resin, polyurethane-urea resin (PUU) is formed, which has good dispersion and wetting properties for pigments.

4.Good resin compatibility

Polyurethane resin for ink has good compatibility with aldehyde-ketone resin, chlorine-vinegar resin, etc. Users can add it appropriately according to the actual situation and their own process formula to improve the overall performance of the ink.

5.Excellent film forming properties

Ink polyurethane resin is structurally different from polyurethane resins used in other fields. Traditional polyurethane mainly reacts with polyester polyol/polyether polyol and isocyanic acid to form hydroxyl-terminated polyurethane resin. The polar group in the molecular structure is carbamic acid. Mainly ester, the molecular cohesion is not enough to meet the film-forming performance requirements of resin for ink.Therefore, polyurethane resin for ink introduces urea group on the basis of traditional polyurethane, which greatly improves the cohesive strength and film-forming properties of the resin itself.

6. Wide compatibility with organic solvents and good solvent release

The dissolving effect of organic solvents on resin is to attract solute molecules through the polarity of solvent molecules, which is commonly known as like miscibility; traditional polyurethane resin has a wide range of compatibility with organic solvents, such as ketones, esters, benzene, etc. Non-alcoholic organic solvents are excellent solvents.However, in the process of making ink, in order to adjust the flow performance and viscosity of the ink, the addition of alcoholic organic solvents is essential. For traditional polyurethane resins, the addition of alcoholic solvents greatly reduces the stability of the resin system, often causing turbidity, Incompatibility phenomena such as flocculent precipitation.However, the presence of urea groups in polyurethane resin for ink makes its compatibility with alcohol a reality. However, it is worth pointing out that alcohol solvents are still pseudo-solvents. In the microscopic state, alcohol solvents wrap the polyurethane resin molecules instead of Like a true solvent, the ink made from polyurethane resin has good fluidity due to the molecular polarity running through the molecule.

 

Applications of polyurethane ink resin

①Selection of solvent

During the ink manufacturing process, considering the volatilization gradient of the overall solvent system of the ink, to improve the solvent release of the printing ink and reduce the organic solvent residue of the printed product solvent, the solvents used are often several mixed solvents with different volatilities.The main organic solvents used in the ink manufacturing process include toluene, methyl ethyl ketone, cyclohexanone, ethyl acetate, butyl acetate, n-propyl acetate, isopropyl alcohol, etc. Customers can adjust the volatility of the ink according to seasonal changes. adjust.

②Selection of pigments

Due to the large differences in pigment grades on the market today, the dispersion and ink stability of the same pigment from different manufacturers of the same resin often vary greatly in polyurethane inks. Therefore, it is recommended that users base their actual needs on their own. Customers need to choose pigments carefully.

③Selection of additives

Wax powder: The wax powder used in the production of polyurethane ink is often low molecular weight polyethylene wax, with a relative molecular weight of generally 1000 to 6000. It has good solubility in the organic solvents in the ink and has affinity with the polyurethane resin itself. Better and has good chemical stability.It mainly serves to increase the friction resistance of the ink film surface, and at the same time, it can appropriately alleviate the anti-stick resistance of the ink itself.

 

Dispersant: A type of surfactant, mainly used to moisten the surface of the pigment, shorten the ink manufacturing time, facilitate the dispersion of the pigment, and sometimes appropriately reduce the oil absorption of the pigment.When manufacturing high-concentration ink, it can reduce the yield value of the ink and prevent the aggregation and precipitation of pigment particles in the ink.

 

Adhesion promoter: The polyurethane resin used for ink contains a large number of polar groups. Even if the surface of non-polar substrates such as BOPP and PE is treated with surface corona, the surface tension is generally between 38 and 42 dynes. To improve the adhesion of polyurethane ink, The adhesion fastness on the surface of this type of substrate often requires the appropriate addition of titanate coupling agents or chlorinated polypropylene adhesion accelerators.

 

Ink binder resin is an extremely critical raw material in the production of ink. It not only serves as a bridge between the color material and the base material, but also gives the ink various excellent physical properties.In ink production, choosing the right resin connecting material directly affects the performance of the ink on various substrates and the process adaptability during the printing process.When selecting resin, the physical properties of the resin must be fully considered to match the performance that the ink needs to achieve.

 

Polyurethane resin is a versatile material that can be used in the preparation of gravure printing ink for film. Gravure printing is a method of printing that uses engraved cylinders to transfer ink onto a substrate, and it is commonly used for high-volume printing applications such as packaging and labeling.

as a binder to provide adhesion and durability to the ink. It can also be used to adjust the viscosity and flow properties of the ink, which is important for ensuring consistent print quality and optimal ink transfer to the substrate.

 

We could provide solvent based polyurethane resin, polyurethane emulsion, acrylic resin, waterborne polyurethane dispersion to meet diversified requirement.

 

What is GRS certification

2024-03-14

GRS (Global Recycled Standard) is a globally recognized certification and labeling system for products made from recycled materials. The purpose of GRS is to promote the use of recycled materials, reduce the environmental impact of production, and provide transparency and assurance to consumers. By using products certified under the Global Recycled Standard, consumers can make more informed choices, supporting sustainability and reducing waste by promoting the use of recycled materials.

 

To achieve GRS certification, companies must meet specific criteria related to the recycled content of their products. This includes ensuring that a minimum percentage of the product's materials come from recycled sources and maintaining traceability throughout the supply chain. GRS also takes into account issues such as environmental management, social responsibility, chemical use, and labeling.

TPU (Thermoplastic Polyurethane) resin can be produced using both virgin and recycled materials. Recycled TPU resin is made from post-industrial or post-consumer waste, which is collected and processed to create new TPU resin. The use of recycled TPU resin helps to reduce waste and conserves resources. Koslen TPU is on the process to obtain GRS (Global Recycled Standard) certification. We can provide GRS (Global Recycled Standard) certification to the industries that standard covered soon, including textiles, apparel, home furnishings, and personal care products.


 


 


 

The proportion of MDI influence the embrittlement performance of TPU at low temperatures

2024-03-14

MDI is one of the key components used in the production of TPUs. It serves as the isocyanate component, reacting with polyols to form the polyurethane segments of TPU.

 

The selection of MDI type and the ratio of MDI to polyols can affect the physical properties and performance characteristics of the TPU, including its low-temperature behavior. TPU formulated with a higher proportion of MDI generally have a higher density of hard segments, which can enhance the stiffness and rigidity of the material. This, in turn, can make the TPU more prone to embrittlement at low temperatures.


 

Therefore, the proportion of MDI in TPU formulations is an essential factor to consider when aiming for specific low-temperature performance requirements. It's crucial to optimize the MDI-to-polyol ratio to achieve the desired balance between hardness, flexibility, and resistance to embrittlement at low temperatures.

 

Research progress and analysis of water-based polyurethane binder

2024-03-08

Summary

The development and innovation of water-based ink connecting materials determines the technological innovation of inks. Water-based polyurethane binder has broad application prospects in the field of water-based inks due to its good wear resistance, adhesive properties, film-forming properties and other advantages. According to the research direction of water-based polyurethane ink application and high performance in recent years, this paper will describe and prospect from three aspects: plastic film printing, inkjet and 3D printing, and anti-counterfeiting water-based polyurethane ink binder preparation and performance research.

 

1 Preparation and performance study of water-based polyurethane ink binder for plastic film printing

 

At present, in the packaging and printing industry, polyolefin films occupy the first place in the printing and packaging film base materials, such as biaxially oriented polypropylene (BOPP) film, polyethylene (PE) film, etc., followed by polyethylene terephthalate glycol. Ester (PET) film, nylon (PA) film, etc. Water-based polyurethane molecular chains contain more polar groups and have high surface tension. Therefore, WPU inks are suitable for surface coating of highly polar substrates such as PET and PA. BOPP, as an important printing substrate, has lower Surface energy, so WPU is difficult to wet on its surface, resulting in poor printing quality [2-4].

 

In order to improve the applicability of WPU ink to the substrate of BOPP film, the main methods currently used are: First, surface treatment such as corona treatment and coating treatment is performed on the film before printing, and polar groups such as carboxyl and hydroxyl groups are introduced to the surface. , to increase the surface tension of the BOPP film, thereby improving the wettability and adhesion of the WPU ink; second, adding adhesion promoters to the water-based ink, such as silicone, chlorinated polypropylene, etc., can reduce the adhesion of the water-based ink. Surface Tension. The third is to carefully design the molecular structure of WPU to reduce the content of polar groups and surface tension in its molecular chain to achieve the goal of improving its printing quality on BOPP films. This is one of the more researched methods currently.

 

Silicone has the advantages of low surface energy, good biocompatibility, high thermal stability and oxygen resistance, and has been widely used in the modification of polyurethane materials [5]. Li et al. [6] studied the blending modification and in-situ modification of WPU emulsion with polyorganosiloxane and found that the use of physical blending method can more effectively reduce the surface energy of WPU. Taking advantage of the low surface energy of fluorine-containing compounds, introducing fluorine-containing groups into waterborne polyurethane molecules can effectively reduce the surface energy of water-based polyurethane and improve hydrophobicity. For example, Xu et al. [7] performed hydroxylation modification of dodecafluoroheptyl methacrylate (DFHMA) to synthesize EDFHMA, then reacted with alcoholized lactide to synthesize fluorine-containing glycol (PLPF), and then reacted with hexamethylene diol Polyurethane was prepared by isocyanate (HDI) reaction. Compared with the control group, the surface energy of WPU containing EDFHMA decreased by nearly 20 mN/m. In addition, relevant studies have shown that grafting long fat side chains into the WPU molecular chain can also reduce the surface tension of WPU, and during the film formation process of WPU, long fat side chains will aggregate to the film surface, which is beneficial to the interaction with low polarity materials. A similar compatibility effect occurs in the BOPP film, which improves the adhesion of WPU on the surface of the BOPP film. Based on this, Zhang et al. [8] used liquid polyester polyol BY3003 with long branched aliphatic chains to prepare WPU latex suitable for BOPP film printing. BY3003 makes the surface tension of the prepared latex not exceed 43 mN/m, while the surface tension of traditional WPU latex exceeds 55 mN/m. Therefore, the T-peel strength of inks made from these latexes is above 0.8 N/15 mm.

 

In addition, the degree of post-chain extension, dimethylol butyric acid content and NCO/OH molar ratio also have a significant impact on the latex and film properties of WPU, especially on the T-peel strength of the corresponding ink. By optimizing these factors, a water-based polyurethane emulsion with a surface tension as low as 39.6 mN/m and an adhesion fastness to BOPP films exceeding 95% was obtained, with a corresponding T-peel strength of ink as high as 2.05 N/15 mm [ 8] .

 

 

 

 

2 Preparation and performance research on water-based polyurethane ink connecting materials for inkjet and 3D printing

 

Inkjet printing has become an essential output method, and research on output devices and printing inks is also continuing to deepen. The printability of an ink is related to transfer and wetting properties such as viscosity, particle size and surface tension, and the coating properties are related to mechanical properties, hardness and aging resistance. In order to obtain WPU ink with excellent performance, Wang et al. [9] used an emulsion polymerization method with WPU as a seed to synthesize core-shell WPUA emulsions with different methyl methacrylate (MMA) contents. As the MMA content in WPUA increases, the average particle size and contact angle of WPUA increase, and the heat resistance and hardness of WPUA coating are enhanced. Inkjet printing inks prepared with WPUA emulsion as base resin show good printability. Yin et al. [10] used isophorone diisocyanate (IPDI), polyol, dimethylol butyric acid (DMBA) and 3,5-dimethylpyrazole (DMP) as raw materials to synthesize a series of block water-based Polyurethane (BWPU). DMP-terminated BWPU has good inkjet fluency and color fastness, and has great potential in digital inkjet printing industrial applications.

 

3D printing, also known as additive manufacturing technology, is the most representative molding technology in current intelligent production. It has the advantages of strong processability and high efficiency. It can be customized according to different needs and is suitable for equipment processing with complex structures. Manufacturing, it has broad application prospects in the fields of aerospace, offshore equipment manufacturing and biomedicine. Compared with traditional polyurethanes, most WPUs have poor mechanical properties, rheological properties, thermal stability and electrical conductivity, and have poor hydrolysis strength in humid environments. In order to overcome the above shortcomings, inorganic fillers such as carbon nanotubes, clay or graphene are usually introduced into the WPU matrix to form organic-inorganic hybrids, thereby improving its performance [11-13].

 

Vadillo et al. [14-15] improved the performance of new polycaprolactone-polyethylene glycol (PCLPEG) water-based polyurethane urea (WBPUU) ink in direct writing 3D by adding cellulose nanocrystals (CNC) in situ as a rheology modifier. Properties in printing technology that can improve the printability and shape fidelity of 3D structures, as well as improve the mechanical and thermal stability of the resulting parts.

 

Chen et al. [16] developed an in-situ synthesis method to modify WPU (WPUCNF) by using cellulose nanofibrils (CNF) to improve its printability. Adding CNF during the emulsification process reduces the size of WPU nanoparticles and increases the viscosity of the suspension. In addition, additional CNF was added to prepare WPUCN/CNF composite ink, which showed excellent printability in various shapes of printing structures such as honeycombs, wood piles, or human ears.

 

The inherent shortcomings of polyurethane such as high melting point and slow degradation rate hinder its application in 3D printing tissue engineering. In view of this, Feng et al. [17] developed a 3D printable amino acid-modified biodegradable water-based polyurethane (WBPU) using a water-based green chemical process. By controlling the content of the hydrophilic chain extender, the printed block has controllable degradation and does not cause the accumulation of acidic products. It is envisioned that it can be used as a biological alternative material for tissue engineering.

 

Currently, 3D printing methods can only create static objects and do not involve any functional changes in intrinsic or extrinsic properties, while 4D printing is defined as the use of 3D printing technology to create materials with active structures that respond to external forces such as heat, magnetism, or light. Stimulated, the material is able to change over time to change the printed 3D shape. There are two main types of polymer materials used for 4D printing: responsive hydrogels and shape memory polymers (SMP). Among various SMPs, polyurethane displays a variety of properties that make it an excellent candidate for 4D printing. For example, in 2019, Su et al. [18] studied the formation of water-based polyurethane coating-based composites as 4D printing precursors by adding carboxymethyl cellulose (CMC) and silicon oxide (SiO2) nanoparticles to the coating.

 

Fused deposition modeling (FDM) is a rapid prototyping method used on 3D printers. In order to prepare WPU materials with excellent comprehensive properties and use them for surface protection of FDM printing products. In order to simultaneously improve the mechanical properties and waterproofness of the WPU membrane, Zhang Jing et al. [19] used in-situ polymerization and surface fluorination to prepare a halloysite nanotube/water-based polyurethane (AHNTs/WPU) composite membrane. The water contact angle increased. As large as 114.5°, it shows better hydrophobicity. A WPU composite film is formed on the surface of FDM. Experimental results show that it can improve the waterproofness and mechanical properties of the sample, and has an obvious surface protection effect.

 

Recently, Zheng Ling et al. [20] used silane coupling agent KH550 to carry out covalent bond functional modification of carbon black (CB), obtained KH550 modified CB, and prepared KH550/CB/WPU composite materials. The CB The addition significantly improves the thermal stability of WPU. The modified CB content was selected to be 3% for the preparation of 3D printing ink. Compared with other non-3D printing products, its conductive properties were improved by 1 to 2 orders of magnitude.

 

In addition, compared with traditional linear macromolecules, the three-dimensional spherical structure of hyperbranched polymers has abundant end groups and lower viscosity, which can provide more modification sites [21] and is therefore widely used in optical applications. Cured coatings, 3D printing photosensitive resin and other fields. Zhang Dongqi et al. [22] prepared hyperbranched water-based polyurethane acrylate by esterifying hyperbranched polyester polyol containing 16 terminal hydroxyl groups with succinic anhydride and reacting with the isocyanate group of isocyanate ethyl acrylate to introduce double bonds. Then, using it as the matrix resin, a series of 3D printing water-based photosensitive resins were prepared by compounding it with the reactive diluting monomers acryloylmorpholine and polyethylene glycol diacrylate. The prepared 3D printing devices have better printing properties. Accuracy.

 

 

3 Preparation and performance research of anti-counterfeiting water-based polyurethane ink connecting material

 

Polymer luminescent materials are widely used in fields such as decoration, anti-counterfeiting, road marking coatings and biomedicine. Fluorescent anti-counterfeiting ink is prepared by blending phosphor powder prepared from polymer fluorescent materials with printing ink. This anti-counterfeiting ink is printed on various packaging materials that require anti-counterfeiting. Under sunlight, the effect is the same as printing with ordinary ink. There is no difference. When a special light source such as an ultraviolet lamp is used to illuminate the fluorescent material, it will show fluorescence of different colors to achieve the identification of authenticity [23]. Wan et al. [24] co-assembled CNC and WPU latex, making full use of the chiral nematic structure of CNC and the flexibility of WPU elastomer to create fast-responsive and flexible photonic paper. Using water or NaCl aqueous solution as ink, it can Make the colorful patterns on CNC/WPU photonic paper temporary, durable, and even camouflaged. Tian Zhen et al. [25] used citric acid and urea as raw materials, used microwave method to synthesize fluorescent carbon dots CDs in one step, and configured two sets of ink samples with self-made ink binders WPU1, WPU2 and related additives. The ink was exposed to 365 nm ultraviolet light. It emits green fluorescence under light irradiation. Wu Jun et al. [26] prepared two types of inks (temperature-changing ink and three-dimensional anti-counterfeiting color-changing ink) for dual anti-counterfeiting QR codes, and studied the effects of different amounts of thermochromic powder on the color difference and chromaticity of the temperature-changing ink, and The effects of foaming temperature, foaming agent content, and WPU resin content on the foaming height and friction resistance of three-dimensional anti-counterfeiting color-changing ink were studied. Zhang et al. [27] designed and synthesized waterborne polyurethane (F-WPU) with polyfluoroalkyl side chains, and used it as a precursor to prepare fluorocarbon quantum dots (F-CD) using a hydrothermal method. F-WPU and F-CDs are mixed with gelatin to obtain environmentally friendly inks for printing on low surface energy substrate PET. FWPU (30wt%) and F-CDs (0.5wt%) significantly improve the mechanical properties of the composite material through the interpenetrating network system and hydrogen bonding. The rich carbon-fluorine bonds effectively reduce the surface energy of gelatin, making it have excellent Hydrophobic, strong adhesion to PET surface. In addition, F-CDs can emit blue-green fluorescence based on the conjugated structure and π→π* transition under a wider excitation wavelength. Therefore, the composite shows good transparency under sunlight and significant cyan fluorescence under ultraviolet irradiation, and can be developed for anti-counterfeiting labels and printing.

 

4 Summary and outlook

 

Water-based polyurethane binder ink will receive more and more attention as an environmentally friendly material. Currently, based on the design, synthesis and application of high-performance WPU connecting materials, scientific and technological workers have made certain research progress in the fields of plastic film printing, inkjet and 3D printing, and anti-counterfeiting. In order to further improve the heat resistance, water resistance, solvent resistance and mechanical properties of WPU, fine water-based polyurethane molecular structure design and controllable preparation research can be carried out for different application fields, such as the synthesis of dendritic polymers and hyperbranched polymers. It has a highly branched structure, particularly low viscosity and good flow properties; it uses controlled "/living" free radical polymerization methods to design and synthesize water-based polyurethane materials with different soft and hard structural sequences and controllable molecular weight and molecular weight distribution. Better analyze the relationship between the structure of WPU connector and the performance of water-based ink. In addition, in the use of traditional inks, color pastes are usually obtained by directly physically blending polyurethane and dye molecules. There are problems such as poor color uniformity, easy discoloration, and poor stability. The dye molecules can be copolymerized with water-based polyurethane substrates. Bonding to obtain a water-based polyurethane-based dye polymer, which has the comprehensive properties of dye chromophore and polyurethane, and is an excellent substitute for traditional color water-based polyurethane inks.

 

Research progress and prospects of polyurethane resin for lamination printingink

2024-03-08

With the development of China's economy and cultural undertakings, the printing and publishing industry and packaging industry have developed rapidly. Domestic demand for ink has increased dramatically. As people's environmental awareness increases and people's demand for safety in food packaging and printing increases, it is required that the proportion of aromatic hydrocarbons and toxic volatile organic components in the ink composition be reduced. Environmentally friendly inks have gradually experienced benzene-free inks, alcohol-soluble inks and water-based inks, and gradually replaced traditional volatile organic solvent-based inks. Polyurethane ink has gradually developed rapidly due to its unique performance advantages. It has the advantages of easy use, stable performance, strong adhesion, excellent gloss, and good heat resistance, and can be suitable for various printing methods. At the same time, polyurethane ink can be dissolved in solvents such as alcohol, ester, ketone or their mixed solvents without relying on highly toxic benzene solvents. It meets environmental protection requirements and has become the development direction and trend of the printing industry. Among the factors that determine the various properties of printing inks, the properties of the resin used in the ink are the main factors. Polyurethane resin has excellent wear resistance, scratch resistance, solvent resistance, bonding properties, good low-temperature performance, high gloss, and heat preservation, and its application properties are widely adjustable and can meet various needs. .

Classification of polyurethane ink

Polyurethane ink can be divided into four main types according to the composition of the binder used and the curing principle: single-component volatile polyurethane ink, two-component reactive polyurethane ink, light-curing polyurethane ink and water-based polyurethane ink ; according to the printing format According to different printing substrates, it can be divided into plastic ink, paper ink, aluminum thin ink, printed fabric ink and ceramic ink, etc. For its special purposes, it can be divided into UV ink, luminescent, fluorescent and phosphorescent ink, liquid crystal, conductive and magnetic ink, retort-resistant ink and anti-counterfeiting ink, etc.

 

Development status of polyurethane resin for ink

2. Polyurethane resin for one-component volatile ink

Volatile polyurethane ink has the advantages of easy use and stable performance, and can meet the requirements of various printing methods. It is mainly used in plastic composite packaging and other aspects. It has been industrialized at home and abroad and has been widely used. The main synthesis mechanism of this type of ink is through the volatilization of a large amount of volatile solvents contained in it, so that the resin and pigment in the ink form a solid film layer that adheres to the surface of the substrate to achieve the purpose of printing. The advantages of this method are uniform reaction, easy control, and good reproducibility. One-component polyurethane resin for ink has good adhesion, oil resistance and cooking resistance on many plastic substrates .

GOLD MINE COMPANY as polyurethane resin manufacturer used adipic acid (AA) and 1,4- butanediol (BDO) as the basic raw materials to synthesize polyester polyols with a relative molecular weight of 1000 to 2000 and chain extenders, diphenylmethane diisocyanate (MDI). A one-component polyurethane ink connecting material is synthesized with other additives. The polyurethane ink has the characteristics of good gloss, low viscosity, and good bonding strength. It can meet the needs of the composite film and ink printing industries. It has been used in Guangdong and Fujian. Promote use in other areas. Zhou Wenxin et al. used a vinyl chloride - hydroxyethyl acrylate copolymer containing hydroxyl groups in the molecule to react with a macromolecular glycol, a small molecule chain extender, and toluene diisocyanate (TDI) to prepare a new type of polyurethane adhesive. The ink produced with it has good adhesion to various base films such as polypropylene (PP) and polyethylene (PE) . A polyurethane resin for inks developed by Japan's Sanyo Chemical Co., Ltd. is composed of polybutylene adipate glycol (PBA , with a maximum relative molecular mass of 1500) , isophorone diisocyanate (IPDI) , and isophorone Made from diamine (IPDA) and diethanolamine, due to the introduction of urea bonds and amine groups, the intermolecular hydrogen bonding force is greatly increased, improving the cohesive strength of the resin and the adhesion to the film. Made of 30 parts of resin and 50 parts of titanium dioxideThe plastic film printing ink prepared by adding 100% and several parts of mixed solvent has good printing effect on PP , polyethylene terephthalate (PET) and nylon films. The printing layer is resistant to heat grease and adhesion.

 

2. Polyurethane resin for two-component reactive ink

Two-component ink is also called chemical reaction ink. A catalyst must be added before printing. The catalyst reacts with the resin in the ink to achieve the purpose of drying the ink through a polymerization reaction. Component A is a hydroxyl-terminated prepolymer and pigment. A mixture of other additives, component B is a curing agent with an isocyanate terminal group. When used, the two components are mixed in a certain proportion to print. This two-component reactive polyurethane ink has good adhesion and viscosity stability to plastic films. Component A has stable performance, low relative molecular weight, good fluidity, and good wettability to pigments; but in component B, due to the presence of isocyanate groups, this component has great Toxicity. In addition, the isocyanate group is a very reactive group and can easily react with water and other compounds containing active hydrogen at room temperature. Therefore, this component has poor stability and is difficult to store. Currently, two-component reactive polyurethane inks have many problems: the main components must be mixed with the curing agent quickly before printing, the ink cannot be touched by hands, the service life of canned products is very short, and the remaining ink after printing is easy to deteriorate. Moreover, the curing agent is expensive, which increases the cost of packaging bags or containers .

 

2.3 Polyurethane resin for photocurable ink

Polyurethane resin for light-curing inks uses high-intensity radiation such as electron beam radiation and ultraviolet radiation to induce cross-linking and curing of the active oligomer system. Considering factors such as equipment investment, ultraviolet (UV) curing is currently the main form. It has the advantages of cold curing, fast curing, energy saving, etc., and due to the use of a 100 % active component system, no solvent is released during the curing process, which greatly reduces pollution. The curing reaction mechanism of light-curing polyurethane ink is free radical polymerization. It can be cured in a few seconds and is suitable for high-speed printing. Since the reaction is a dry cross-linking process, it has good adhesion to most substrates. As a new type of environmentally friendly ink, UV curable ink has the advantages of energy saving, no solvent emission, no environmental pollution, high production efficiency, suitable for heat-sensitive substrates, excellent printing performance, and low equipment investment. It is widely used in paper and plastics , metal, paint film and other printing surfaces are extremely widely used. The entire curing system of UV curing is a solvent-free system, which is in line with green and environmentally friendly inks. UV ink printing has stable adaptability, can improve actual production efficiency and reduce costs, and can bring economic benefits such as high productivity and high output to investors .

 

2.4 Polyurethane resin for water-based ink

Water-based inks are listed as the first choice for environmentally friendly printing. The normal temperature cross-linked water-based polyurethane epoxy adhesive can produce a one-component polyurethane water-based ink suitable for gravure printing. The water-based ink has high gloss and water resistance, strong adhesion, adjustable dryness, bright colors, clear layers, non-toxic, non-flammable, weather-resistant, The viscosity is easy to control, and compared with other water-based inks, it has wide adaptability to various substrate materials. Polyurethane-polyacrylic acid. As a connecting material for water-based ink, during the drying process of ink film prints, the properties of polyurethane epoxy adhesive and polyacrylate are combined. The modified emulsion also has good adhesion fastness to the film. Compared with water-based acrylate, epoxy resin, etc., water-based polyurethane resin has more advantages in wear resistance, water resistance, chemical resistance, impact resistance, and balance of flexibility and hardness. Since it does not contain volatile organic solvents, it improves It improves the working environment, completely eliminates toxic and harmful substances in solvent-based inks, and eliminates contamination of packaged goods. It is mainly used for rotogravure printing machines to print food bags, shopping bags, fresh milk packaging bags, pharmaceutical packaging bags, sausage bags, candy bags, beverage bags, children's bags on EDM-treated PE , PP , PET, PVC and other films. Toy packaging bags and other packaging and printing products; at the same time, it is beneficial to protect the health of printing workers and consumers, reduce environmental pollution, etc., and represents the development direction of modern printing. Due to its own advantages and good compatibility with other resins, water-based polyurethane inks are constantly being improved and opening up more and more extensive application fields. At present, water-based polyurethane inks have been commercialized, can meet a variety of performance requirements, and are receiving more and more attention. The main applications of water-based polyurethane ink are flexographic printing and gravure printing. Water-based polyurethane ink, which is widely used abroad, is environmentally friendly and has good ink performance. It is mainly characterized by stable ink properties, high brightness, strong tinting power, and high adhesion fastness. , the drying speed can adapt to the needs of printing speed, and both four-color overprinting and spot color printing are available E1-M011a MM[27] uses IPDI and polyethylene glycol (PEG, with relative molecular masses of 1000 and 2000) and hydroxyethyl methacrylate, using dibutyltin dilaurate as a catalyst, a water-based polyurethane was synthesized. The polyurethane has low viscosity, good fluidity, high dyeing strength and good environmental protection, and can be used in food packaging and medical supplies.

 

Prospects of polyurethane resin for ink

In recent years, the domestic plastic packaging industry has been changing rapidly, and the consumption of ink has increased significantly year by year. As people's living standards continue to improve, the demand for packaging inks is bound to further increase. Currently, our country accounts for 1/4 of the world's population, but our country's total ink production is less than 1/10 of the world's total production . The per capita consumption of ink is less than 1/24 of the world's top three average levels . The per capita consumption of printed matter is less than 1/24 of the world's average . It is still less than 1/20 of developed countries Such a large gap shows that there is broad space for the development of my country's ink and the market development potential is huge. As people's environmental awareness gradually increases and people's demand for safety in food packaging and printing increases, the original benzene-containing ink connectors, although they have excellent performance, will eventually be eliminated because they are too toxic. Polyurethane ink connecting materials will develop rapidly in the future due to their unique performance advantages and environmental protection characteristics.

In addition, as China has become the fastest growing economy in the Asia-Pacific region, the world's major ink manufacturers have made major investment activities in China, such as Toyo Ink, SakataInx DIC , Flint Ink, Donghua Ink, etc. In order to occupy the Chinese polyurethane ink market, many foreign companies have invested and built factories in China. Japan's Takeda Pharmaceutical Company's production plant in Suzhou has been put into production, providing ordinary low-priced polyurethane resins for inks to the Chinese market. The American Rohm and Haas Company has also set up a factory in Shanghai. After acquiring Morton Company, in addition to vigorously promoting water-based adhesives, it also sells polyurethane resins for solvent-based inks.

 

Tips and Tricks for VAE Emulsion CW40-707 Unleash the Power of Vinyl Acetate-Ethylene Copolymer Emulsion

Are you an enthusiast of VAE Emulsion (Vinyl Acetate-Ethylene Copolymer Emulsion)? If so, you’re in the right place! In this blog post, we’ll dive into the world of VAE Emulsion CW40-707 and share with you some valuable tips and tricks to make the most of this remarkable product.

1. Understanding VAE Emulsion CW40-707

Before we delve into the tips, let’s get familiar with VAE Emulsion CW40-707. This particular formulation is known for its high-quality vinyl acetate-ethylene copolymer emulsion. CW40-707 offers excellent adhesive and binding properties, making it ideal for a wide range of applications in the building and construction industry.

2. Proper Storage and Handling

To ensure the best performance and extend the shelf life of VAE Emulsion CW40-707, it’s crucial to store and handle it correctly. Here are a few guidelines:

  • Store the emulsion in a cool, dry place away from direct sunlight and extreme temperatures.

  • Avoid exposure to freezing temperatures, as it can negatively affect the stability of the emulsion.

  • Always seal the container tightly after use to prevent contamination or moisture absorption.

3. Mixing and Dilution

When working with VAE Emulsion CW40-707, it’s essential to know the appropriate mixing and dilution techniques. Follow these tips for optimal results:

  • Stir the emulsion well before use to ensure proper homogeneity.

  • Dilute the emulsion with clean water at the recommended ratio to achieve the desired viscosity for your application.

  • Use a proper mixing tool, such as a low-speed mechanical stirrer, to ensure uniformity during the dilution process.

4. Surface Preparation

For the best adhesion and bonding performance, proper surface preparation is key. Consider these points:

  • Clean the surface thoroughly, removing any dirt, dust, or grease.

  • Repair any cracks or imperfections in the substrate before applying the emulsion.

  • Ensure the surface is dry and free from any moisture that may affect the bonding process.

5. Application Techniques

Achieving the desired results with VAE Emulsion CW40-707 requires proper application techniques. Here are a few tips:

  • Apply the emulsion evenly using a brush, roller, or spray application method.

  • Follow the recommended coverage and drying time as specified by the manufacturer.

  • Apply multiple coats if needed, ensuring proper drying between each layer.

6. Safety Precautions

As with any chemical product, it’s important to prioritize safety when working with VAE Emulsion CW40-707. Here are a few safety precautions to bear in mind:

  • Wear appropriate protective clothing, gloves, and goggles to avoid direct contact with the emulsion.

  • Work in a well-ventilated area to prevent the inhalation of fumes.

  • If any skin or eye contact occurs, immediately rinse with plenty of water and seek medical advice if necessary.

With these tips and tricks, you’re well-equipped to maximize the potential of VAE Emulsion CW40-707 in your projects. Explore its versatility and enjoy the superb adhesive and binding properties it offers for your building and construction needs!

Remember, mastering the art of using VAE Emulsion is a journey, so don’t be afraid to experiment, learn from experience, and share your knowledge with fellow enthusiasts in the community. Happy crafting!

How to Get Glucosamine Naturally

2024-03-01

Glucosamine, also known as glucosamine, is a natural compound that plays a vital role in our bodies. It is a major component in building and repairing joint cartilage, so getting enough glucosamine is very important for those concerned about joint health. So, how can we naturally obtain this valuable nutrient from food or lifestyle?

 

The most natural way to get glucosamine is through food. Although not many foods directly contain glucosamine, there are some foods that can be converted into glucosamine during digestion. For example, shrimp, crab, and other crustaceans are rich in chitosan, the precursor to glucosamine. Eating these foods regularly can help your body naturally produce glucosamine.

 

Getting glucosamine naturally isn't just about eating certain foods, it's about your overall lifestyle. By choosing foods rich in glucosamine precursors, keeping our joints healthy, and making healthy lifestyle choices, we can ensure our bodies get enough glucosamine to keep our joints healthy and flexible.

 

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Is Chitosan Water Soluble

2024-03-01

Chitosan is a naturally occurring polymer derived from chitin, which is found in the exoskeletons of crustaceans such as shrimp and crabs. One of the key properties of chitosan is its water solubility. However, the solubility of chitosan in water depends on its degree of deacetylation (the extent to which the chitin has been modified).

 

Chitosan, in its natural form, is insoluble in water due to the presence of acetyl groups attached to the polymer chain. However, through a process called deacetylation, the acetyl groups are removed, resulting in a more water-soluble form of chitosan known as chitosan hydrochloride. This form of chitosan readily dissolves in acidic solutions, such as hydrochloric acid, since protonation of the amino groups occurs, making it water-soluble.

 

While native chitosan is insoluble in water, modified forms such as chitosan hydrochloride and other derivatives have improved water solubility. This characteristic opens up opportunities for various applications in the fields of food, biomedical, and pharmaceutical industries.

 

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